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Identification and ecotoxicity assessment of intermediates generated during the degradation of clofibric acid by advancedoxidation processes

Wenzhen LI, Yu DING, Qian SUI, Shuguang LU, Zhaofu QIU, Kuangfei LIN

《环境科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 445-454 doi: 10.1007/s11783-012-0419-6

摘要： The aim of this study was to identify the intermediates in clofibric acid degradation under various advanced oxidation processes, namely ultraviolet (UV), UV/H O , vacuum ultraviolet (VUV), VUV/H O , and solar/TiO processes, as well as to assess the toxicity of these intermediates. Eleven intermediates have been detected by gas chromatography-mass spectrometer, most of which were reported for the first time to our best knowledge. Combining the evolution of the dissolved organic carbon, Cl and specific ultraviolet absorption at 254 nm, it could be deduced that cleavage of aromatic ring followed by dechlorination was the mechanism in solar/TiO process, while dechlorination happened first and accumulation of aromatic intermediates occurred in the other processes. Different transformation pathways were proposed for UV-, VUV-assisted and solar/TiO processes, respectively. The acute toxicity was evaluated by means of T spp. bioassay. It was believed that aromatic intermediates increased the toxicity and the ring-opening pathway in solar/TiO process could relieve the toxicity.

关键词： clofibric acid     advanced oxidation processes     intermediates     toxicity     Photobacterium phosphoreum T3 spp.    

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Oxidation and biotoxicity assessment of microcystin-LR using different AOPs based on UV, O

Siyi Lu, Naiyu Wang, Can Wang

《环境科学与工程前沿（英文）》 2018年 第12卷 第3期 doi: 10.1007/s11783-018-1030-2

摘要： Microcystin-LR attracts attention due to its high toxicity, high concentration and high frequency. The removal characteristics of UV/H O and O /H O advanced oxidation processes and their individual process for MC-LR were investigated and compared in this study. Both the removal efficiencies and rates of MC-LR as well as the biotoxicity of degradation products was analyzed. Results showed that the UV/H O process and O /H O were effective methods to remove MC-LR from water, and they two performed better than UV-, O -, H O -alone processes under the same conditions. The effects of UV intensity, H O concentration and O concentration on the removal performance were explored. The synergistic effects between UV and H O , O and H O were observed. UV dosage of 1800 mJ·cm was required to remove 90% of 100 g·L MC-LR, which amount significantly decreased to 500 mJ·cm when 1.7 mg·L H O was added. 0.25 mg·L O , or 0.125 mg·L O with 1.7 mg·L H O was needed to reach 90% removal efficiency. Furthermore, the biotoxicity results about these UV/H O , O /H O and O -alone processes all present rising trends with oxidation degree of MC-LR. Biotoxicity of solution, equivalent to 0.01 mg·L Zn , raised to 0.05 mg·L Zn after UV/H O or O /H O reaction. This phenomenon may be attributed to the aldehydes and ketones with small molecular weight generated during reaction. Advice about the selection of MC-LR removal methods in real cases was provided.

关键词： Microcystin-LR     Advanced oxidation processes (AOPs)     Biotoxicity     Synergistic effects    

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Identification of resistant pharmaceuticals in ozonation using QSAR modeling and their fate in electro-peroxone process

《环境科学与工程前沿（英文）》 2021年 第15卷 第5期 doi: 10.1007/s11783-021-1394-6

摘要：

• Effect of converting ozonation to E-peroxone was studied on pharmaceutical removal.

关键词： Ozone     Electro-peroxone     Wastewater     Quantitative structure activity relationship     Advanced oxidation processes    

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Transfer-Promoted Fe2+/Fe3+ Circulation Steered by 3D Flow-Through Co-Catalyst System Toward Sustainable AdvancedOxidation Processes

Weiyang Lv,Hao Li,Jinhui Wang,Lixin Wang,Zenglong Wu,Yuge Wang,Wenkai Song,Wenkai Cheng,Yuyuan Yao,

《工程（英文）》 doi: 10.1016/j.eng.2023.06.010

摘要： Realizing fast and continuous generation of reactive oxygen species (ROSs) via iron-based advanced oxidation processes (AOPs) is significant in the environmental and biological fields. However, current AOPs assisted by co-catalysts still suffer from the poor mass/electron transfer and non-durable promotion effect, giving rise to the sluggish Fe2+/Fe3+ cycle and low dynamic concentration of Fe2+ for ROS production. Herein, we present a three-dimensional (3D) macroscale co-catalyst functionalized with MoS2 to achieve ultra-efficient Fe2+ regeneration (equilibrium Fe2+ ratio of 82.4%) and remarkable stability (more than 20 cycles) via a circulating flow-through process. Unlike the conventional batch-type reactor, experiments and computational fluid dynamics simulations demonstrate that the optimal utilization of the 3D active area under the flow-through mode, initiated by the convection-enhanced mass/charge transfer for Fe2+ reduction and then strengthened by MoS2-induced flow rotation for sufficient reactant mixing, is crucial for oxidant activation and subsequent ROS generation. Strikingly, the flow-through co-catalytic system with superwetting capabilities can even tackle the intricate oily wastewater stabilized by different surfactants without the loss of pollutant degradation efficiency. Our findings highlight an innovative co-catalyst system design to expand the applicability of AOPs based technology, especially in large-scale complex wastewater treatment.

关键词： Advanced oxidation processes     3D co-catalyst     Flow-through mode     Enhanced mass transfer     Complex wastewater treatment    

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Increasing significance of advanced physical/chemical processes in the development and application of

RULKENS Wim

《环境科学与工程前沿（英文）》 2008年 第2卷 第4期   页码 385-396 doi: 10.1007/s11783-008-0073-1

摘要： The awareness of the problem of the scarcity of water of high quality has strongly changed the approach of wastewater treatment. Currently, there is an increasing need for the beneficial reuse of treated wastewater and to recover valuable products and energy from the wastewater. Because microbiological treatment methods are, only to a limited part, able to satisfy these needs, the role and significance of physical/chemical processes in wastewater treatment are gaining more and more interest. The specific future role and aim of the various physical/chemical treatment processes can be categorized in five groups: improvement of the performance of microbiological treatment processes, achievement of the high quality required for reuse of the effluent, recovery of valuable components and energy from the wastewater for beneficial reuse, desalination of brackish water and seawater, and treatment of concentrated liquid or solid waste residues produced in a wastewater treatment process. Development of more environmentally sustainable wastewater treatment chains in which physical/chemical processes play a crucial role, also requires application of process control and modeling strategies. This is briefly introduced by the elaboration of treatment scenarios for three specific wastewaters.

关键词： control     beneficial     valuable     scarcity     Development    

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DNAN的高级氧化过程研究 Article

苏海磊, Christos Christodoulatos, Benjamin Smolinski, Per Arienti, Greg O´Connor, 孟晓光

《工程（英文）》 2019年 第5卷 第5期   页码 849-854 doi: 10.1016/j.eng.2019.08.003

摘要：

2,4-二硝基茴香醚（DNAN）是用于替代2,4,6-三硝基甲苯（TNT）的钝感炸药的一种重要成分。为了研究初始pH和过氧化氢（H2O2）剂量对DNAN降解动力学和降解途径的影响，开展了DNAN的光催化H2O2氧化实验。结果显示，初始pH为4~7且H2O2剂量为1500~4500 ppm，使用UV/ H2O2处理浓度为250 ppm的DNAN溶液时，DNAN的降解服从零级反应动力学。但是，当H2O2剂量为750 ppm时，DNAN的降解服从类一级反应动力学。结果表明，DNAN易于被UV/H2O2氧化降解。当H2O2剂量为1500 ppm且初始pH为7时，3 h内DNAN浓度从250 ppm降到1 ppm以内；但3 h内总有机碳（TOC）和总碳（TC）浓度从100 ppm降到70 ppm以下，9 h后降到5 ppm以下，说明生成了其他有机化合物。这些中间产物氧化为CO2的速度慢于DNAN的氧化速度。UV/H2O2氧化过程中，生成的CO2释放到空气中，因为溶液pH迅速降低到3左右。9 h的UV/H2O2处理后，DNAN中的N绝大多数转化为硝态氮。研究表明，UV/H2O2氧化是处理DNAN废水的有效技术。

关键词： 2     4-二硝基茴香醚     高级氧化技术     废水处理     光催化    

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Accelerated degradation of orange G over a widepH range in the presence of FeVO

Xiaoxia Ou, Jianfang Yan, Fengjie Zhang, Chunhua Zhang

《环境科学与工程前沿（英文）》 2018年 第12卷 第1期 doi: 10.1007/s11783-018-1013-3

摘要： In this study, FeVO was prepared andused as Fenton-like catalyst to degrade orange G (OG) dye. The removalof OG in an aqueous solution containing 0.5 g·L FeVO and 15 mmol·L hydrogen peroxide at pH 7.0 reached 93.2%. Similar rates were achievedat pH 5.7 ( = 0.0471 min ), pH 7.0 ( = 0.0438 min ), and pH 7.7 ( = 0.0434 min ). The FeVO catalyst successfullyovercomes the problem faced in the heterogeneous Fenton process, i.e.,the narrow working pH range. The data for the removal of OG in FeVO systems containing H O conform to the Langmuir–Hinshelwood model ( = 0.9988),indicating that adsorption and surface reaction are the two basicmechanisms for OG removal in the FeVO –H O system. Furthermore, the irradiationof FeVO by visible light significantly increasesthe degradation rate of OG, which is attributed to the enhanced ratesof the iron cycles and vanadium cycles.

关键词： Azo dye     Degradation     FeVO4     Kinetics     Advanced oxidation processes    

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Enhanced triallyl isocyanurate (TAIC) degradation through application of an O

Yapeng Song, Hui Gong, Jianbing Wang, Fengmin Chang, Kaijun Wang

《环境科学与工程前沿（英文）》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1243-z

摘要： Abstract • UV/O3 process had higher TAIC mineralization rate than O3 process. • Four possible degradation pathways were proposed during TAIC degradation. • pH impacted oxidation processes with pH of 9 achieving maximum efficiency. • CO32– negatively impacted TAIC degradation while HCO3– not. • Cl– can be radicals scavenger only at high concentration (over 500 mg/L Cl–). Triallyl isocyanurate (TAIC, C12H15N3O3) has featured in wastewater treatment as a refractory organic compound due to the significant production capability and negative environmental impact. TAIC degradation was enhanced when an ozone(O3)/ultraviolet(UV) process was applied compared with the application of an independent O3 process. Although 99% of TAIC could be degraded in 5 min during both processes, the O3/UV process had a 70%mineralization rate that was much higher than that of the independent O3 process (9%) in 30 min. Four possible degradation pathways were proposed based on the organic compounds of intermediate products identified during TAIC degradation through the application of independent O3 and O3/UV processes. pH impacted both the direct and indirect oxidation processes. Acidic and alkaline conditions preferred direct and indirect reactions respectively, with a pH of 9 achieving maximum Total Organic Carbon (TOC) removal. Both CO32– and HCO3– decreased TOC removal, however only CO32– negatively impacted TAIC degradation. Effects of Cl– as a radical scavenger became more marked only at high concentrations (over 500 mg/L Cl–). Particulate and suspended matter could hinder the transmission of ultraviolet light and reduce the production of HO· accordingly.

关键词： Triallyl isocyanurate     O3/UV     Advanced oxidation processes (AOP)     Degradation pathway    

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The performance of nitrate-reducing Fe(II) oxidation processes under variable initial Fe/N ratios: The

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1366-2

摘要：

•Bacterially-mediated coupled N and Fe processes examined in incubation experiments.

关键词： Denitrification     N2O emission     Fe(II) oxidation     Fe/N ratio     Fe minerals    

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光驱高级氧化技术在新兴污染物零排放中的应用现状与挑战

王大伟, Allyson L. Junker, Mika Sillanpää, 蒋一兰, 魏宗苏

《工程（英文）》 2023年 第23卷 第4期   页码 19-23 doi: 10.1016/j.eng.2022.08.005

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Combined process of biofiltration and ozone oxidation as an advanced treatment process for wastewater

Xinwei LI,Hanchang SHI,Kuixiao LI,Liang ZHANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第6期   页码 1076-1083 doi: 10.1007/s11783-015-0770-5

摘要： The effluent of a wastewater treatment plant was treated in a pilot plant for reclaimed water production through the denitrification biofilter (DNBF) process, ozonation (O ), and biologic aerated filtration (BAF). The combined process demonstrated good removal performance of conventional pollutants, including concentrations of chemical oxygen demand (27.8 mg·L ) and total nitrogen (9.9 mg·L ) in the final effluent, which met the local discharge standards and water reuse purposes. Micropollutants (e.g., antibiotics and endocrine-disrupting chemicals) were also significantly removed during the proposed process. Ozonation exhibited high antibiotic removal efficiencies, especially for tetracycline (94%). However, micropollutant removal efficiency was negatively affected by the nitrite produced by DNBF. Acute toxicity variations of the combined process were estimated by utilizing luminescent bacteria. Inhibition rate increased from 9% to 15% during ozonation. Carbonyl compound concentrations (e.g., aldehydes and ketones) also increased by 58% as by-products, which consequently increased toxicity. However, toxicity eventually became as low as that of the influent because the by-products were effectively removed by BAF. The combined DNBF/O /BAF process is suitable for the advanced treatment of reclaimed water because it can thoroughly remove pollutants and toxicity.

关键词： wastewater treatment     micropollutant removal     ozonation     biofiltration     toxicity    

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Numerical modeling of mass transfer processes coupling with reaction for the design of the ozone oxidation

Hong Li, Fang Yi, Xingang Li, Xin Gao

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 602-614 doi: 10.1007/s11705-020-1963-4

摘要： A computational model for an ozone oxidation column reactor used in dyeing wastewater treatment is proposed to represent, simulate, and predict the ozone bubble process. Considering the hydrodynamics, mass transfer, and ozone oxidation reaction, coupling modeling can more realistically calculate the ozone oxidation bubble process than the splitting methods proposed in previous research. The modeling is validated and shows great consistency with experimental data. The verified model is used to analyze the effect of operating conditions, such as the initial gas velocity and the ozone concentration, and structural conditions, such as multiple gas inlets. The ozone consumption is influenced by the gas velocity and the initial ozone concentration. The ozone’s utilization decreases with the increasing gas velocity while nearly the same at different initial ozone concentrations. Simulation results can be used in guiding the practical operation of dyeing wastewater treatment and in other ozonation systems with known rate constants in wastewater treatment.

关键词： ozone     wastewater treatment     numerical simulation     mass transfer    

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The main anammox-based processes, the involved microbes and the novel process concept from the application

《环境科学与工程前沿（英文）》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1487-1

摘要：

• The PNA, denitratation/anammox, and DAMO/anammox process are reviewed together.

关键词： Anammox     Nitritation     Denitratation     Denitrifying anaerobic methane oxidation     Mainstream wastewater    

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Impacts of advanced treatment processes on elimination of antibiotic resistance genes in a municipal

Lian Yang, Qinxue Wen, Zhiqiang Chen, Ran Duan, Pan Yang

《环境科学与工程前沿（英文）》 2019年 第13卷 第3期 doi: 10.1007/s11783-019-1116-5

摘要：

The distributions of ARGs were monitored in a WWTP in Harbin during six months.

CASS had the best removal efficacy of ARGs compared to other processes in the WWTP.

UV disinfection could effectively control the HGT.

AGAC significantly remove ARGs and organics due to its high absorption capacity.

Combination of ozone and AGAC significantly improve removal of ARGs and organics.

关键词： Antibiotic resistance genes (ARGs)     Wastewater treatment plant (WWTP)     Ultraviolet (UV)     Ozonation     Granular activated carbon (GAC)    

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Oxidative treatment of aqueous monochlorobenzene with thermally-activated persulfate

Qishi LUO

《环境科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 188-194 doi: 10.1007/s11783-013-0544-x

摘要： The oxidation of aqueous monochlorobenzene (MCB) solutions using thermally- activated persulfate has been investigated. The influence of reaction temperature on the kinetics of MCB oxidation was examined, and the Arrenhius Equation rate constants at 20°C, 30°C, 40°C, 50°C, and 60°C for MCB oxidation performance were calculated as 0, 0.001, 0.002, 0.015, 0.057 min , which indicates that elevated temperature accelerated the rate. The most efficient molar ratio of persulfate/MCB for MCB oxidation was determined to be 200 to 1 and an increase in the rate constants suggests that the oxidation process proceeded more rapidly with increasing persulfate/MCB molar ratios. In addition, the reactivity of persulfate in contaminated water is partly influenced by the presence of background ions such as Cl , , , and . Importantly, a scavenging effect in rate constant was observed for both Cl and but not for other ions. The effective thermally activated persulfate oxidation of MCB in groundwater from a real contaminated site was achieved using both elevated reaction temperature and increased persulfate/MCB molar ratio.

关键词： persulfate     monochlorobenzene     advanced oxidation process    

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标题 作者 时间 类型 操作

Identification and ecotoxicity assessment of intermediates generated during the degradation of clofibric acid by advancedoxidation processes

Wenzhen LI, Yu DING, Qian SUI, Shuguang LU, Zhaofu QIU, Kuangfei LIN

期刊论文

Oxidation and biotoxicity assessment of microcystin-LR using different AOPs based on UV, O

Siyi Lu, Naiyu Wang, Can Wang

期刊论文

Identification of resistant pharmaceuticals in ozonation using QSAR modeling and their fate in electro-peroxone process

期刊论文

Transfer-Promoted Fe2+/Fe3+ Circulation Steered by 3D Flow-Through Co-Catalyst System Toward Sustainable AdvancedOxidation Processes

Weiyang Lv,Hao Li,Jinhui Wang,Lixin Wang,Zenglong Wu,Yuge Wang,Wenkai Song,Wenkai Cheng,Yuyuan Yao,

期刊论文

Increasing significance of advanced physical/chemical processes in the development and application of

RULKENS Wim

期刊论文

DNAN的高级氧化过程研究

苏海磊, Christos Christodoulatos, Benjamin Smolinski, Per Arienti, Greg O´Connor, 孟晓光

期刊论文

Accelerated degradation of orange G over a widepH range in the presence of FeVO

Xiaoxia Ou, Jianfang Yan, Fengjie Zhang, Chunhua Zhang

期刊论文

Enhanced triallyl isocyanurate (TAIC) degradation through application of an O

Yapeng Song, Hui Gong, Jianbing Wang, Fengmin Chang, Kaijun Wang

期刊论文

The performance of nitrate-reducing Fe(II) oxidation processes under variable initial Fe/N ratios: The

期刊论文

光驱高级氧化技术在新兴污染物零排放中的应用现状与挑战

王大伟, Allyson L. Junker, Mika Sillanpää, 蒋一兰, 魏宗苏

期刊论文

Combined process of biofiltration and ozone oxidation as an advanced treatment process for wastewater

Xinwei LI,Hanchang SHI,Kuixiao LI,Liang ZHANG

期刊论文

Numerical modeling of mass transfer processes coupling with reaction for the design of the ozone oxidation

Hong Li, Fang Yi, Xingang Li, Xin Gao

期刊论文

The main anammox-based processes, the involved microbes and the novel process concept from the application

期刊论文

Impacts of advanced treatment processes on elimination of antibiotic resistance genes in a municipal

Lian Yang, Qinxue Wen, Zhiqiang Chen, Ran Duan, Pan Yang

期刊论文

Oxidative treatment of aqueous monochlorobenzene with thermally-activated persulfate

Qishi LUO

期刊论文